Evaluating intergranular corrosion with metallography and xps chemical analysis. Intergranular stress corrosion cracking tends to occur when preexisting inter granular fractures are present. The environmental and metallurgical factors in the intergranular stress corrosion cracking of austenitic stainless steel at temperatures below 100 c has been examined. Intergranular stress corrosion cracking igscc of austenitic stainless steels, usually aisi 304 steel, is a serious problem in boiling water reactors bwr. Study on the mechanism of intergranular stress corrosion. In the presence of tensile strength, cracking may occur along grain boundaries and this type of corrosion is frequently called interranular stress corrosion cracking igscc or simply intergranular corrosion cracking. Intergranular corrosion an overview sciencedirect topics. Room temperature stress corrosion cracking of titanium. In both cases, igscc occurs through the nucleation, growth, and linkup of grain boundary voids rather than by grain boundary dissolution. Intergranular stress corrosion cracks in 7030 brass exposed to ammo. The objectives are to characterize the grain boundary microstructure and the fracture mechanism of igscc in az31 mg alloy. It is associated with the simultaneous presence of a number of factors.
Introduction stress corrosion cracking scc may be defined as the delayed failure of alloys by. Intergranular corrosion is localized attack along the grain boundaries, or immediately adjacent to grain boundaries, while the bulk of the grains remain largely unaffected. Intergranular cracks follow the grain boundaries in the metal. In this study, a grain boundary model with threedimensional 3d cohesive elements for analyzing the intergranular stress corrosion cracking igscc on the crystal level in polycrystalline materials is presented. A computational model for intergranular stress corrosion cracking. What is intergranular stress corrosion cracking igscc. The mechanism of elevated temperature intergranular cracking. Stress corrosion cracking international institute of. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Effects of irradiation on intergranular stress corrosion cracking. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be. Intergranular stress corrosion cracking igscc has been studied in two similar nickelbase alloys, alloys 600 and x750, in deaerated steam at elevated temperatures 380 c. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2. The cracks were generally observed in the heat affected zone haz of thick components or of attachment welds.
There are several other processes that can lead to intergranular fracture, or preferential crack propagation at the grain boundaries. Postweld heat treatment to avoid stress corrosion cracking twi. Intergranular stress corrosion cracking an overview. Scc is well known as the major mechanism of alloy 600 sg tubing. The intergranular corrosion is called interdendritic corrosion or intercrystalline corrosion. Occasionally, both types of cracking are observed in a failure. In some cases, however, corrosion fatigue and stress corrosion cracking can occur simultaneously to exhibit unique and accelerated crack growth. Impurityinduced reduction of intergranular cohesion a major factor limiting the usable strength level of ultrahighstrength steels is particularly severe when aggravated by mobile hydrogen through environmental interaction, as in the case of hydrogen stress corrosion cracking. This paper deals with intergranular stress corrosion cracking igscc mechanisms in nibase alloys in various corrosive environments such as deaerated water, airsaturated chloride medium, and caustic solutions at high temperatures with focus on cr content and. Stress corrosion cracking in aluminum alloys is characteristically intergranular.
Transgranular stress corrosion cracking of highpressure. Intergranular corrosion and stress corrosion larissacglima. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. Sensitization refers to the precipitation of carbides at grain boundaries in a stainless steel or alloy, causing the steel or alloy to be susceptible to intergranular corrosion or intergranular stress corrosion cracking. How to reduce the risk of intergranular corrosion igc materials with less than 0. Intergranular stress corrosion cracking igscc is a mode of subcritical crack propagation in susceptible nickelbased alloys and austenitic stainless steels used in power generation. Firstprinciple studies available in the literature are used for characterizing the process of intergranular. Intergranular corrosion or intergranular cracking was occurred on the surface of pdeoxidized 12h and o copper tubes under.
This form of cracking is generally referred to as reheat cracking and is associated to. Corrosion behavior of the stressed sensitized austenitic. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. On the stress corrosion cracking and hydrogen embrittlement. The mechanism of intergranular corrosion was summarized by sinyavskii et al. Kallol mondal,department of metallurgy and material science,iit kanpur. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Dec 19, 2019 intergranular stress corrosion cracking igscc is a type of corrosion due to applied forces on the granular boundaries of a material. Intergranular stress corrosion cracking of copper a case study. Timetofailure tests and crackgrowthrate tests are widespread practices for studying the response of various materials undergoing scc. It can lead to unexpected sudden failure of normally ductile metal. The relationship between igc and scc susceptibility and the mechanisms of scc in aa6005a extrusions were studied by examining two primary hypotheses. To clarify the acidic intergranular stress corrosion cracking igscc mechanism of alloy 600, some metallurgical factors were extracted from the various igscc contributing factors, and several kinds of experimental studies were conducted.
Specifically, this type of corrosion occurs as a result of the boundaries of grains being more susceptible to. Modelling of intergranular stress corrosion cracking mechanism. Intergranular stress corrosion cracking igscc cracks propagate along the grain boundaries. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Then, the stress corrosion cracking mechanism for various materials in.
The photos above show the microstructure of a type 304 stainless steel. Stress corrosion cracking of facecenteredcubic alloys. The relationship between corrosion fatigue and stress. The presence of flaws that concentrate stress or crevices that alter. Postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels. Investigation of stress corrosion cracking of austenitic, duplex and. Transgranular corrosion is also known as intragranular corrosion and transcrystalline corrosion. The electrochemical polarization curves showed an obvious second current peak for the sensitized alloys which indicated the existence of second phase in the structure and the presence of intergranular stress corrosion cracking. Stress corrosion cracking can proceed in one of two ways.
Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline. The obtained data indicates an interesting mechanism that governs intergranular stress corrosion cracking. The microstructure of metals and alloys is made up of grains, separated by grain boundaries. Intergranular stress corrosion cracking of welded steel twi. Stress corrosion cracking of mild steels by nitrate solutions is well known.
Modelling intergranular stress corrosion cracking in. The stress corrosion cracking behavior of austenitic stainless steels in. Observations show that dislocations, are subject to preferential dissolution, and are the principal sites of crack initiation in both intergranular and transgranular modes of failure. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Acoustic emission during intergranular stress corrosion cracking. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Stress corrosion cracking behavior of alloy 600 coupled to. The stress corrosion cracking scc of aluminum alloys is a welldocumented phenomenon, but there is considerable disagreement in the scientific literature as to what mechanism causes it.
Microstructural and microchemical mechanisms controlling. Clscc chloride stress corrosion cracking mechanism china. Intergranular stress corrosion cracking of austenitic. Based on the present study, the grain boundary area is composed of the carbide interfaces at which an. Intergranular corrosion igc can seriously weaken the bonding force between crystal grains and the mechanical strength of metals and alloys would be markedly damaged due to igc. Dec 09, 2017 intergranular stress corrosion cracking igscc is defined as cracking that occurs along the grain boundaries of crystallites due to corrosion.
Intergranular stress corrosion cracking igscc of alloy 600 in hightemperature, deaerated water or steam has been termed hydrogeninduced igscc. Intergranular corrosion induced by environmental stresses is termed stress corrosion cracking. Selective dissolution of the pearlite nodules, which can be catalyzed by chlorides, occurs in fge and this effect stops the propagation of the intergranular scc crack leading to a localized corrosion at the pearlite nodule. Stress corrosion cracking scc is interpreted to take place due to specific combinations of susceptible materials in suitable corrosion environments under adequate stress, specifically under constant stress, figure 1. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Bruemmer b a departments of nuclear engineering and materials science and engineering, university of michigan, ann arbor, mi 48109, usa b pacific northwest laboratory, richland, wa 993. The behavior of annealed and sensitized microstructures in a variety of environments, including oxygencontaining pure water and aqueous solutions containing species such as.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. It has been known for more than 10 years that titanium alloys suffer from intergranular stress corrosion cracking if they are in contact with chlorides. Microstructural and microchemical mechanisms controlling intergranular stress corrosion cracking in lightwaterreactor systems stephen m. Intergranular corrosion degradation and surface engineering. Mechanistic differences in transgranular and intergranular. Transgranular stress corrosion cracking of highpressure pipelines in contact with solutions of near neutral ph r. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. We believe these cracks are initiated by the nucleation of a high density of bubbles on the grain. Combined true corrosion and stress corrosion fatigue. Together, these two phenomena have been known to cooccur, causing numerous failures in a wide variety of industries. Welded steel pipelines that are used to transport oil and gas under high pressure have been known to fail by stress corrosion cracking scc, and the cracking can be intergranular, transgranular, or a combination of both, depending on the environmental and operational conditions. Grain boundary selective oxidation and intergranular. Transgranular cracking is a key characteristic of chloride induced stress corrosion cracking in austenitic stainless steels.
Both intergranular and transgranular stress corrosion cracking are. In consequence, intergranular corrosion attack iga and stress assisted intergranular corrosion attack saiga in general called stress corrosion cracking can occur in carbon steel construction materials. Intergranular stress corrosion cracking of core shrouds. One model, for example, is the embrittlement model. The postulated mechanisms for stress corrosion cracking of. A joint industry project is described, that tested the current understanding of the mechanism of sensitisation to intergranular stress corrosion cracking of welded. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. Feb 06, 2011 intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the bulk of t he grains remain largely unaffected igc is associated. The core shroud is among the list of internals susceptible to igscc.
The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. However, the time required for crack initia tion is strongly dependent on a wide variety of pa rameters, such as surface finish. Other problems that have been observed with inconel include wastage, tube denting, pitting, and intergranular attack. Electron microscopy has been used to study the initial stages of stress corrosion cracking in some single phase copperbased alloys and an austenitic steel. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. The mechanism of cracking in both these modes and the conditions under which the transition from tram to intergranular cracking or vice versa occur are topics of much debate and research, some recent work have suggested that the mechanism of trans and intergranular stress corrosion cracking are identical, in this study, by using the load. Temperature is a significant environmental factor affecting cracking. This is, of course, a very complex question for a forum like this. To establish the mechanism of elevated temperature intergranular cracking, it is considered the case in which the composition p600 and the tensile stress.
The combination of stress and igc, for some alloysenvironment systems will cause intergranular stress corrosion cracking igscc zhou and zuo, 2015. According to the electrochemical theory, this requires a condition along grain boundaries that makes them anodic to the rest of the microstructure so that corrosion propagates selectively along them. Mod01 lec27 pitting corrosion, intergranular corrosion. The interaction of corrosion fatigue and stresscorrosion.
The interaction between a propagating intergranular stress corrosion crack and the microstructure has been investigated by insitu three dimensional observations of intergranular stress corrosion cracking, using the id19 xray microtomography beam line at the european synchrotron radiation facility esrf, france 4. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steelelectrolyte interface, which are formed by the applied cathodic current to protect the structure 71. Modelling of intergranular stress corrosion cracking mechanism kth. Fontana corrosion center, department of materials science and engineering b. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Evaluating intergranular corrosion with metallography and xps.
This form of corrosion cracking is caused by a combination of tensile stresses on the material in the presence of corrosive conditions. A research program focused on understanding the intergranular corrosion igc and stress corrosion cracking scc behavior of aa6005a aluminum extrusions is presented in this dissertation. Stress corrosion cracking scc near the fusion boundary of a 316ng stainless steel ss welded joint in hightemperature water was investigated with emphasis on the relation to the. Figure 43 an example of intergranular cracking of pipeline steel revie 2000. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking. Scc propagation was mainly transgranular, but scc propagation of. Intergranular stress corrosion cracking is common in alloys that are otherwise typically corrosionresistant. While corrosion fatigue and stress corrosion cracking can occur under different circumstances, they are recognized as being part of the same continuum. Intergranular stress corrosion cracking igscc is more common than transgranular scc. According to webcorr 2014, there is no specific mechanism to explain stress corrosion cracking.
Cracking of sensitized stainless steels inspectioneering. Intergranular and transgranular stress corrosion cracking of. Intergranular stress corrosion cracking of copper a case. Introduction the mechanism of transgranular stress corrosion cracking tgscc. The present understanding may enable rational design and. Transgranular stress corrosion cracking tgscc cracks run through the individual grains. The equivalent mechanism for crack growth under cyclic stresses is called corrosion fatigue cf, and crack growth here depends upon the stress ratio. Jun 05, 2017 mod01 lec27 pitting corrosion, intergranular corrosion duration. In this chapter, the conditions for the occurrence of scc are first introduced. Characterization of intergranular stress corrosion cracking. Effects of irradiation on intergranular stress corrosion cracking g. Figure 3 illustrates this behavior, where the red line is a superposition of the crack growth rates expressed in figure 1 and figure 2. Transition from intergranular corrosion to intergranular. Bruemmer materials sciences department, pacific northwest laboratory, richland, wa 99352, usa gary s.
Inter granular corrosion can be detected by ultrasonic and eddy current methods. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Delanty introduction the majority of instances of stress corrosion cracking scc in highpressure gas pipelines has been associated with the propagation of intergranular cracks. Intergranular corrosion facts and how to reduce the risk. On the mechanism of intergranular corrosion of aluminum alloys. Paper presented at stainless steel world 2005 conference, maastricht, the netherlands, 810 november 2005. The driving force of intergranular corrosion is the difference between the electrode potentials of the grain boundary and the grain itself, which form a galvanic cell in presence of an electrolyte. A mechanism for hydrogeninduced intergranular stress. With high enough stress level the intergranular scc mechanism can change to transgranular scc cracking at the pearlite. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Rokhlin department of industrial, welding, and systems engineering, the ohio state university, columbus, ohio 43210, usa the transition of intergranular corrosion igc to intergranular stress corrosion cracking igscc in.
Though it is easy to identify intergranular cracking, pinpointing the cause is more complex as the mechanisms are more varied, compared to transgranular fracture. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. Simulating intergranular stress corrosion cracking in az31. Intergranular corrosion igc, also known as intergranular attack iga, is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. Nitrate stress corrosion cracking in waste heat recovery. This is because of the intermolecular space that exists due to the interaction of two or more components. Recognize the mechanism for igscc and the conditions that make igscc more likely. Stress corrosion cracking scc is a very common failure mechanism characterized by a slow, environmentally induced crack propagation in structural components. The driving force of intergranular corrosion is the difference between the electrode potentials of the grain boundary and the grain itself, which form a. Scc was severe in type 304, moderate in types 316l and 304ln, and very slight in types 304nh and 316nh. Intergranular corrosion igc microstructure of metals and alloys is made up of grains separa ted by grain boundaries intergranular corrosion is a localized attack along the grain bo undaries, or immediately adjacent to grain boundaries, while the.